STATISTICAL THERMODYNAMICS AND EXCESS MOLAR VOLUMES OF SOME TERNARY AND QUATERNARY LIQUID MIXTURES AT 298.15 K.
journal of kerbala university,
2016, Volume 12, Issue 4, Pages 2-9
AbstractThe statistical mechanical concept of Flory has been extended for the theoretical prediction of excess molar volume of ternary and quaternary solutions assuming two-body interactions . The validity of the developed expressions has been tested for four ternary solutions and quaternary solutions .Surprisingly , the agreement between theory and experiment was found to be quite satisfactory for the excess molar volume in both sign and value.
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